Everything about Quicklime totally explained
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Calcium oxide (
CaO), commonly known as
burnt lime,
lime or
quicklime, is a widely used
chemical compound. It is a white,
caustic and
alkaline
crystalline solid. As a commercial product, lime often also contains
magnesium oxide,
silicon oxide and smaller amounts of
aluminium oxide and
iron oxide.
Calcium oxide is usually made by the thermal decomposition of materials such as
limestone, that contain
calcium carbonate (CaCO
3; mineral name:
calcite) in a
lime kiln. This is accomplished by heating the material to above 825°
C, a process called
calcination or
lime-burning, to liberate a molecule of
carbon dioxide (CO
2); leaving CaO. This process is reversible, since once the quicklime product has cooled, it immediately begins to absorb
carbon dioxide from the air, until, after enough time, it's completely converted back to
calcium carbonate. Calcination of limestone is one of the first chemical reactions discovered by man and was known in
prehistory.
Up until the
20th century, quicklime was used as a disinfectant, usually in a 10% solution called milk of lime. However, it had the disadvantage of decomposing rapidly on exposure to air and moisture, and the burnt lime had to be fresh and unslaked.
Usage
As hydrated or
slaked lime, Ca(OH)
2 (mineral name:
portlandite), it's used in
mortar and
plaster to increase the rate of hardening as well as to improve adhesion.
Hydrated lime is very simple to make as lime is a basic
anhydride and reacts vigorously with
water. Lime is also used in
glass production and its ability to react with silicates is also used in modern metal production (
steel,
magnesium,
aluminium and other metals) industries to remove impurities as
slag.
It is also used in water and sewage treatment to reduce
acidity, to soften, as a
flocculant, and to remove
phosphates and other impurities; in
paper making to dissolve
lignin, as a
coagulant, and in
bleaching; in agriculture to improve acidic
soils; and in
pollution control, in gas scrubbers to
desulfurize waste gases and to treat many liquid effluents. It has traditionally been used in the burial of bodies in open graves, to hide the smell of decomposition, as well as in forensic science, to reveal fingerprints. It is a
refractory and a dehydrating agent and is used to purify
citric acid,
glucose,
dyes and as a CO
2 absorber. It is also used in pottery, paints and the food industry. Furthermore, quicklime is used in epidemics, plagues, and disasters to disintegrate bodies in order to help fight the spread of disease. CaO is a key ingredient in the nixtamalization process used to create corn hominy and masa or tortilla dough.
A relatively inexpensive substance, CaO produces heat energy by the formation of the hydrate, as in the following equation:
» :CaO + H2O ↔ Ca(OH)2 + 63.7kJ/mol of CaO
The hydrate can be reconverted to calcium oxide by removing the water in the reversible equation. If the hydrated lime is heated to redness, the CaO will be regenerated to reverse the reaction. As it hydrates, an exothermic reaction results. One litre of water combines with approximately 3.1kg of calcium oxide to give calcium hydroxide plus 3.54MJ of energy. This process can be used to provide a convenient portable source of heat, as for on-the-spot food warming in a self-heating can.
World lime annual production is around 130 million metric tons, with the USA and China the largest producers, each producing around 20 million metric tons.(External Link
)Further Information
Get more info on 'Quicklime'.
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